Steam methane reformer reactor design bookshelf

Solar methane steam reforming msr uses an endothermic chemical reaction to convert methane and steam to syngas carbon monoxide and natural gas, which has an approximately 27% higher heating. A conventional steam reformer unit consists of several hundred fixedbed reactor tubes filled with a catalyst, which can vary in size and geometry. The steam methane reforming process is the most widespread method for the hydrogen production. The present work discusses the mathematical modeling and the control design of the steam reforming of natural gas. Steam methane reforming simulation hydrogen production. Researchers from the technical university of denmark and haldor topsoe, with colleagues from the danish technological institute and sintex have developed a disruptive approach to a fundamental process by integrating an electrically heated catalytic structure directly into a steam methane reforming smr reactor for hydrogen production. The lis database is a collection of household income surveys. Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas.

The gas produced by the steam reforming reaction first passes through a shift reactor, where carbon monoxide converts to carbon dioxide and hydrogen. Equipment design and cost estimation for small modular biomass systems, synthesis gas cleanup, and oxygen separation equipment. The steam methane reforming process can be broken down into five distinct steps. The main chemical reactions that participate in the steam methane. The outlet temperature of cogeneration heat exchanger is analyzed to be applied as a feed of steam reformer. Pdf basic design of tubular steam reformer chathura. The steam reforming plant consists of four basic sections bressan et al. I just want to know how i would use this information to design the reformer. It consists of a reformer with multiple additional components for pre and post processing. Optimization of a methane autothermal reforming bas ed hydrogen production system with low co 2 emissions wei wu,a and chutima tungpanututh b adepartment of chemical engineering, national cheng kung university, tainan 70101, taiwan, r. Autothermal reforming of natural gas to synthesis gas. Sep 19, 2016 methane steam reforming was carried out in a conventional packed bed reactor pbr to experimentally demonstrate the effect of process intensification and the presence of the secondary catalyst. Followed by a purification step using inhousestandard 4 or 5bed psa technology. Syngas production the global syngas technologies council.

Pretreatment process, reformer reactor, shift reactor, gas purification process. To this end, complex mathematical models that describe the integrated system are developed to study different design prospects and to determine. Design of process plant for producing hydrogen from steam. The syngas stream contains h 2, co, co 2, and unconverted ch 4 and process steam. The water gas shift reactor is filled with an ironchrome based catalyst that causes steam h 2o to break into oxygen and hydrogen. Design the modular plant is designed to meet exact.

This is usually combined with psa to purify the hydrogen to greater than 99. Process design simulation of h2 production by sorption enhanced. After comparing the process to methane steam reforming, it was found that glycerol steam reforming in a packed bed reactor is a feasible solution for the transformation of waste into a clean sustainable commodity. Reactor design and catalysts testing for hydrogen production. Videos you watch may be added to the tvs watch history and. The lab scale tests allowed for the design of the benchscale reactor. Onsite hydrogen generation by steam methane reforming. Much of the gas delivery high pressure tubing and flow control was offtheshelf equipment. The thermodynamic equilibrium in steam reforming methane reactor can be. Equipment design and cost estimation for small modular. Steam reforming is the dominant method for hydrogen production. Leaving the shift reactor, the gas contains approximately 75 vol% hydrogen, with carbon dioxide, carbon monoxide and some unconverted methane plus nitrogen if this was present in the feed to the. This paper discusses simulations of reactive flows in a twodimensional cylindrical bubbling fluidized bed reactor by using an eulerian modeling approach. Therefore, there have been several alternative configurations developed that utilize a heat exchange reformer concept.

In this context, steam methane reforming coupled with carbon capture through membrane separation is emerging as a potential route for hydrogen generation with a reduced carbon footprint. This paper presents the design, fabrication, and successful realcondition testing of a solar microreactor for hydrogen synthesis via steam methane reforming smr. Aspen plus for reactor design and optimization intro. Modeling of sorption enhanced steam methane reforming in an. Cfd modeling and control of a steam methane reforming reactor. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. Kinetics study and modelling of steam methane reforming. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst.

The equilibrium composition out of the steam reformer is shown in fig. Kinetics study and modelling of steam methane reforming process over a nioal 2o 3 catalyst in an adiabatic packed bed reactor s. Microkinetic model assisted design for steam methane reforming. Computational fluid dynamics in chemical reactor analysis. Integration of methane steam reforming and water gas shift. Given the intrinsic kinetics, the tortuosity factor of a nimgal 2 o 4 catalyst was determined under reaction conditions by minimizing the sum of squares of residuals of the exper. Reaction and transport in industrialscale packed bed steam. The reactors are heated by different means depending on the reactor type see below.

Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of. Model for steam reforming of ethanol using a catalytic wall. Advanced modelling and optimisation of natural gas reforming. This reformer is often called tubular fired reformer because of the reactor design.

Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Smr is a costeffective and energy efficient way of producing hydrogen. Simulation and control of steam reforming of natural gas. In steam methane reforming applications, the reforming furnace is a large piece of equipment and it has flue gas heat losses that have to be minimized through a complex waste heat recovery section. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0. In practice, an smr unit can contain from 40 to tubes, each of which is typically 612 m long, 70160 mm in diameter, and 1020 mm in wall thickness. We focused on determining the crucial factors of reactor design, especially for commercializing methane reforming reactions, by conducting a series of. The gproms advanced model library for fixedbed reactors aml. Solutions for the mathematical models of the fixedbed reactor and the membrane reactor, equations 7 and 8, resulted in several plots for the conversion of methane. Plugflow reactors are very common in methane steam reforming applications. Benchscale steam reforming of methane for hydrogen. The model yields data of heat transfer, temperature and. Syngas production in what is called steam methane reforming, hightemperature steam 700c1,000c is used to produce raw syngas from a methane source, typically natural gas.

Improving downfired steam methane reforming flue gas. With regard to methane reformingbased hydrogen production processes, a combination of partial oxid ation and steam reforming of methane in an autothermal reform ing atr reactor has recently become more popular. This name is commonly retained even when other feedstocks e. Wood awarded multimillion dollar steam methane reformer contract. Methane steam reforming an overview sciencedirect topics.

The tubular reactor design for a steam reformer in figure 1 a schematic representation of a hydrogen production system on the basis on methane conversion is shown. Kjersti omdahl christensen steam reforming of methane on. These modular hydrogen plants are based on inhouse steam reforming technology employing a round upfired can reformer type design. The second is the steam methane reformer, which converts feedstock and steam to syngas mainly hydrogen and carbon monoxide at high temperature and moderate pressure. Figure 2 conventional design for small scale steam methane reformers 38 50. Modeling and simulation of an industrial secondary. Standard conditions used to simulate the behavior of the methane steam reforming process in the conventional fixedbed reactor and the membrane reactor can be seen in table 1. Water enters the furnace, producing steam at a very high temperature.

Developed a dynamic, multiscale, heterogeneous model for catalytic steam methane reforming reactors that allows for particle level tracking in concentration and temperature without using a catalyst specific effectiveness factor a first for steam methane reforming models. In energy, smr is the most widely used process for the generation of hydrogen 2 if playback doesnt begin shortly, try restarting your device. The model of a parallelplate reformer was studied by settar et al. Hello, ive been asked to design a primary reformer for the extraction of hydrogen from methane for haber bosch process final year project. Pcis osr technology for reforming methanol based fuels was developed under a dod program for military portable power and has demonstrated thermal efficiency greater than 87% with co concentration in the reformate as low as 1. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Steam methane reforming hydrogen production air liquide. The steam reactor contains a 3x6 inventory space for holding components. An optimal operational window of a ghsv range from 1050 to 14,000 h. Johnson matthey process technologies is a leader in reforming technology for the industrial production of hydrogen, methanol and ammonia to the chemicals and oil and gas sectors. Modelling optimisation of process and design parameters for minimising natural gas consumption in hydrogen production by steam reforming sanke rajyalakshmi, kedar patwardhan and p v balaramakrishna larsen and toubro. Stabilize steam methane reformer combustion, reduce variability, and gain control of energy costs with emersons steam methane reformer solution, which will enable your operators to respond to changing conditions, keep your equipment from degrading and failing, and help stabilize your reformers performance. Water gas shift reactor additional hydrogen is created in the water gas shift reactor.

Danish team electrifies steammethane reforming for. Optimizing a steammethane reformer for hydrogen production. The strong endothermic steam reforming reaction might result in a temperature drop at the inlet of the reactor. For decades, downfired steam methane reformer furnaces have utilized flue gas tunnels aka coffins along the radiant section floor to collect and improve flue gas flow uniformity. Just you need to know the flow rate of methane ch4 of how much hydrogen to produce from the reformer. A fluidized bed membrane reactor for the steam reforming of. In these scenarios, the steam reforming of natural gas still arises as the key hydrogen production technology in the short term, whereas water electrolysis is the main technology in the medium and. The secondary reformer is a part of a subprocess in a higher scale unit of ammonia synthesis. Optimization of a methane autothermal reformingbased. The first is feedstock treatment where sulphur and other contaminants are removed.

Steam reformer material and energy balance youtube. The integrated design with small characteristic length scales allows compact reactor designs, potentially 100 times smaller than current reformer. The suggested design is basically a fluidized bed reactor equipped with a bundle of membrane tubes. Compact steammethane reforming for the production of hydrogen. Hydrotreating and hydrocracking process training course. Steam reforming of methane in metalfoam filled reactor. Where only pure h2 is required as product, a water gas shift step is employed using steam as reactant to convert most of the co in raw syngas to co2.

Kinetics, catalysis and mechanism of methane steam reforming. Steam reforming of ethanol using a novel reactor configuration, called catalytic wall reactor, was successfully studied using comsol. An innovative chemistry model was developed in which the reactive rate j and volume expanding rate. Redefining steam methane reformer performance in hydrogen production diane dierking johnson matthey process technologies.

Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. Technologies for hydrogen, carbon monoxide, and syngas. The labscale tests allowed for the design of the benchscale reactor. Many research and development programs are investigating the development of steam methane reforming technologies to enable the transition to sustainable energy, because it is considered that hydrogen can play a key role as an energy carrier. The steam methane reformer is widely used in industry. It involves the diffusion of reactants through bulk of gases to the surface of the catalyst particles and within the porous particles. This comprehensive course overlays the process fundamentals and sound knowledge of hydrotreating and hydrocracking processes where hydrogen is a key material in the upgrading and treatment of refinery products and fractions.

The ser reactor operation must be described using a dynamic model due to the timedependent nature of co2 capture, as shown in fig. The equation shows the moles reacted of ch4 and h2o. Steam reforming of methane in metalfoam filled reactor was studied in this paper. Feb 22, 20 reformer design calculation posted in student. Additionally, some systems use an internal indirect reformer that has the form of a. Advanced modelling and optimisation of natural gas. The design of the steam reforming process is in part dictated by these constraints. Under these conditions, the catalyst presents the average h2co. Sorption enhancement of chemical processes, volume 51 compiles the latest, stateoftheart progress in the area of sorption enhanced processes.

For the steam reforming process, several types of reactors are possible, such as conventional reformers with top ignition or side ignition, which are widely used. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Hydrogen production via steam reforming with co2 capture. The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled. As an energy carrier, hydrogen has the potential to boost the transition toward a cleaner and sustainable energy infrastructure. Steam methane reforming simulation hydrogen production hysys tutorial p sims. The methane steam reformer heated up by the molten salt stream is modelled in detail by a twodimensional mathematical model based on mass, energy and momentum balances with the intrinsic kinetic equations reported by xu and froment. The reactor system has two lines, one passing through the reformer, and another bypassing the reformer. These tunnels range from 4 to 10 feet high, 2 to 3 feet wide, and 40 to 100 feet long, depending on the unit design capacity. Using a steam methane reformer smr, methane reacts with steam under 325 bar of pressure in the presence of a catalyst to produce hydrogen, carbon monoxide, and a. A life cycle assessment lca of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases, as well as other major environmental consequences. On the other hand, the process of combined reforming utilizes both of primary and secondary tools for production of synthesis gas, as it is commonly practiced in ammonia manufacturing.

In addition to computing the microkinetic model, experimental work for methane steam reforming was conducted. The developed model comprises a set of differential and algebraic equations, based on energy and mass balances for reactions performed in a fixed catalyst bed reactor, where natural gas and water are transformed mainly into a mixture of hydrogen and carbon oxides. Lca is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes. They showed that proper distribution of a catalyst can improve the efficiency of a methane steam reformer, but only thin catalyst layers coated to the reformer wall were considered. Solar enriched methane production by steam reforming process. In this paper, the industrial secondary reformer reactor has been modeled and simulated at steadystate operation conditions. A compact and efficient steam methane reformer for hydrogen.

Steam reforming of methane is a vital unit operation in the manufacture of synthesis gas or syngas. Comsol multiphysics was selected because is an ideal tool for coupling transport mechanisms mass, momentum, and heat transfer with chemical reactions. I am required to design a steam reformer alongside a furnace for a design project. Therefore, the reaction mixture can be analysed before and after the reaction. Steam methane reformers hydrogen ammonia methanol syngas gtl bd energy systems have executed more than 90 steam methane reformer projects which include lumpsum revamp and turnkey epc projects and cover a full range of equipment supply and services. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. This dissertation presents initial developments on ngr modelling in gproms. Hydrogen production from methane steam reforming with co2.

The majority of the worlds syngasproducing plants apply steam methane reforming, with the specific type of reforming technology depending on application and operating conditions. The study is intended to elucidate some aspects of high relevance for the development of novel concepts in the area of hydrogen production by means of steam methane reforming smr. Methane steam reforming reaction behaviour in a packed. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. The reaction front that evolves with time generates a gas composition as a function of the operating conditions in the reaction front.

Meanwhile, the steam methane reformer refers only to the fired chemical reactor in which reaction takes place. Their operation presents many challenges, such as a strong dependence on temperature and inlet composition distribution. The syngas from the reformer further goes through a water gas shift reactor where co and steam react to form h 2 and co 2. This study aims to analyze the feasibility of heat application design of rde reactor in the steam methane reforming for hydrogen production using the chemcad software. Life cycle assessment of hydrogen production via natural gas. Topics in this updated volume include sorptionenhanced watergasshift and steam methane reforming, co2 sorbents for sorption enhanced steam reforming, reactor design for sorption enhanced reforming using cacu chemical loops, sorptionenhanced. Co are also active for the methane steam reforming 25. Autothermal reforming atr uses oxygen and carbon dioxide or steam in a reaction with methane to form syngas. Steam methane reforming smr is a process in which methane from natural gas is heated, with steam and a catalyst, to produce synthetic fuel. For each steam reactor chamber adjacent to the steam reactor, one additional column is added, to a maximum space of 9x6. Determine the outlet composition from a steam reforming reactor using both material and energy balances. As mentioned before, the major advantage of the cmr compared to a conventional pbr is the conversion enhancement of the equilibriumlimited msr by.

It is located after the primary reformer in the ammonia plant where it is used in the. This thesis considers the design and operational feasibility of heat integrating two conventional industrial processes gasification and steam reforming of methane for application in polygeneration. The reaction takes place in a single chamber where the methane is partially oxidized. Nrel award aco544027, equipment design and cost estimation for small modular biomass systems, synthesis gas cleanup and oxygen separation equipment. Mahmud school of chemical and process engineering, the university of leeds, ls2 9jt, uk. Sorption enhancement of chemical processes, volume 51. Topsoe offers several types of reforming technologies and has decades of experience ensuring that the optimal design is selected for each individual project. Methane steam reforming reaction behaviour in a packed bed. The conventional steam methane reformer consists of a furnace that contains tubes in it, with catalyst loaded in these tubes to speed up the rate of the reaction r1 21. Steam methane reforming smr and autothermal reformer atr are two industrial examples of the primary and secondary reformers, respectively. The future of gastoliquids plants phoenix equipment. These data points for ni and rh catalyst were plotted against the model to see how well the simulation predicted the. Towards a thermal optimization of a methanesteam reforming.

The lis project began in 1983 under the joint sponsorship of the. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. The steam methane reformer for simplicity, it is denoted as reformer in the following text is the core unit in a smr process which has a process tube side and a furnace side that interact through heat exchange through the walls of reforming reactors for simplicity, they are denoted as the reforming. In smr the reaction proceeds inside a number of reformer tubes while heat is being transferred from a furnace radiant chamber. Pci is developing a compact steam reforming reactor sr. The steam reactor has two 8000mb fluid tanks, one for water, one for steam. Process analysis of solar steam reforming of methane for producing. The reactor comprises a plurality of plates in a stack, as a fullscale design usually includes hundreds to many thousands of parallel flow. Sevan marine, sgs, shearwater geoservices, shelf drilling, shell. Danish team electrifies steammethane reforming for greener. Atr autothermal reactor pox partial oxidation steam methane reformer smr smr is one of the predominant technologies for producing raw syngas a gas mixture of hydrogen and carbon monoxide. Computational fluid dynamics in chemical reactor analysis and design.